A. A. Fil'chikov scite author profile

The parent 30-electron triple-decker iron complex with cyclopentadienyl [igands, [(q-CsHs)Fe(ta-rI:q-Cst|5)Fe(q-CsHs)]PF 6 (i), was prepared for the first time by visiblelight irradiation of ferroccnc and [(ri-CsHs)Fe(q-C6H6)IPF 6 in CH2CI 2 at 0 ~ An analogous reaction performed with the use of (rI-CsHs)Co(q-C4Me 4) (2) instead of ferrocene afforded the thermally labile 30-electron cationic iron-cobalt triple-decker complex [(q-CsIts)Fe(~-q:q-CsHs)Co(q-C4Me4)}PF 6. The latter reacted with compotmd 2 at 20 ~ to form the symmetrical 30-electron cationic dicobalt triple-decker complex [(q-C4Me4)Co(~tq:q-C5Hs)Co(q-C4Me4)] PF6.

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Participation of hydrogen bonds in the protonation of (?5-C5Me5)M(CO)2, M=Ir, Rh

Shubina

Крылов

Muratov

et al. 1993

Russ Chem Bull

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Synthesis of triple-decker iron and cobalt complexes with a central tetramethylphospholyl ligand

et al. 2000

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Deprotonation and Subsequent Functionalization of Methyl Groups in Cationic Ruthenium Triple-decker Complexes

Kudinov

Fil'chikov

Rybinskaya

1992

Mendeleev Communications

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A. A. Fil'chikov

(Tetramethylcyclobutadiene)cobalt Complexes − Syntheses of Tris(ligand) Derivatives and Structures of [(C4Me4)Co(CO)3]BF4 and [(C4Me4)Co(NCMe)3]PF6

30-Electron cationic iron- and cobalt-containing triple-decker complexes with a central cyclopentadienyl ligand. The first synthesis of the parent triple-decker iron complex with cyclopentadienyl ligands, [(η-C5H5)Fe(μ-η:η-C5H5)Fe(η-C5H5)]PF6

Participation of hydrogen bonds in the protonation of (?5-C5Me5)M(CO)2, M=Ir, Rh

Synthesis of triple-decker iron and cobalt complexes with a central tetramethylphospholyl ligand

Deprotonation and Subsequent Functionalization of Methyl Groups in Cationic Ruthenium Triple-decker Complexes

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