Die nach Literaturangaben dargestellten Methylencyclopropane (I) werden nach dem Verfahren von Doering oder Makosza mit Dichlor‐ bzw. Dibromcarben in die Titelverbindungen (II) übergeführt.
The reaction of benzil with methyl alkyl ketones gave three isomeric cyclopentenone derivatives, 2-substituted and cis-and trans-5-substituted 4-hydroxy-3,4-diphenylcyclopent-2-en-1-ones. cis-and trans-2,5-Disubstituted 4-hydroxy-3,4-diphenylcyclopent-2-en-1-ones were formed in analogous reaction of benzil with dialkyl ketones. The structure of the products was confirmed by 1 H NMR spectroscopy and molecularmechanics calculations.
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