Rotational transitions of several hydrogen-bonded complexes between formic acid and water have been observed with a pulsed nozzle Fourier transform microwave spectrometer between 8 and 26 GHz. Three sets of rotational transitions have been assigned with the help of their Stark effects and of microwave–microwave double resonance experiments to formic acid–water, formic acid–(water)2 and (formic acid)2–water. Rotational constants and some centrifugal distortion constants have been fitted for each complex, and the components of the permanent electric dipole moments have been determined from Stark splittings. Structures and binding energies from ab initio calculations have been determined to the observed formic acid–water complexes.

The rotational spectra of three benzene–X complexes, where X=20Ne, 129Xe, or 132Xe, and of the benzene-1,3,5-d3–Ar complex have been observed using pulsed nozzle Fourier transform microwave (FTMW) spectroscopy. Rotational transitions assigned in the 8–18 GHz range have been found to match symmetric top spectra. Rotational constants B and centrifugal constants DJ and DJK were determined from the measured frequencies. Intermolecular motions between benzene and the rare gas atom have been modeled with a rovibrational Hamiltonian. The three-dimensional interaction potential has been assumed of a simple form with three adjustable parameters. These parameters, one of which represents the equilibrium distance of the rare gas atom from the plane of benzene, have been adjusted for all benzene–rare gas complexes in a least-squares fit by direct inversion of the observed rotational transition frequencies. From the potential, the force constants and frequencies of the van der Waals vibrations and the binding energies have been deduced for all benzene–rare gas complexes.

We report a detailed spectroscopic investigation of the chiral molecule bromochlorofluoromethane (CHBrClF) with rotational resolution using a pulsed nozzle beam Fourier transform microwave (FTMW) and a waveguide FTMW spectrometer as well as a supersonic jet interferometric Fourier transform infrared (FTIR) and infrared diode laser spectrometer. The rotational spectrum of CHBrClF has been measured between 8 and 18 GHz. The quadrupole hyperfine components have been fully resolved for the assigned rotational transitions with J⩽18. Three ground state rotational constants, five centrifugal distortion constants, and all five independent elements of the bromine and chlorine quadrupole coupling tensors have been determined for each of the four isotopomers CH79Br35CIF, CH81Br35CIF, CH79Br37CIF, and CH81Br37CIF from about 500 measured transition frequencies of the hyperfine components. The quadrupole coupling tensor has been transformed to its principal axes. The determinable sign combinations of the off-diagonal elements of the coupling tensor have been evaluated. Rotational transitions involving high J were measured by FTIR spectroscopy between 15 and 40 cm−1 (450–1200 GHz) using a light pipe cell, providing an estimate of the permanent dipole moment |μ|=(1.5±0.3) D from intensities. In the midinfrared, we have fully analyzed the rovibrational line structure of supersonic jet spectra of the CF-stretching fundamental ν4, giving band centers for the isotopomers CH79Br35CIF [ν̃ 40=1077.178 43(4) cm−1], CH81Br35CIF [ν̃=1077.133 06(4) cm−1], CH79Br37CIF [ν̃ 40=1076.7914(4) cm−1], and CH81Br37CIF [ν̃ 40=1076.730 26(5) cm−1]. A combined analysis of about 20 microwave frequencies, more than 100 infrared ground state combination differences, and about 70 infrared transition frequencies for each of the35Cl isotopomers finally provide accurate ground and excited state rotational parameters as well as structural parameters, which may be compared to ab initio calculations. The results are discussed in relation to the molecular structure as well as coincidences of ν4 absorptions with CO2 laser lines in view of CO2–laser pumping and possible spectroscopic studies of this chiral molecule at ultrahigh resolution.

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