Research has been carried out on the manufacture of tungsten indicator electrodes with a diameter of 1 mm coated with PVA-Enzyme coated with PVC-KTpClPB using the biosensor potentiometer method. It has a sensitivity of 19,096 mV/decade, a detection range of 1.10-5 - 5.10-4 M, a detection limit of 1.10-5 M and a correlation coefficient of R2 = 0.9431. This detection range is very small, only a difference of one order to the negative power. On the basis of this small range, the PVA-Enzyme and PVA-Enzyme-GA solutions have been characterized by UV-vis showing a very clear difference in the width of the absorbance peak at wavelength. The indicator electrodes B1-4 and B3-4 have been analyzed using UV-vis, FTIR, SEM-eds and XRD. The method used is the biosensor poteniometric method, urease enzyme immobilization technique, which analytes urea in determining sensitivity, detection range and detection limit, as well as variable signal analysis of 60 signals/second. The results obtained from the indicator electrode B1-4 have a sensitivity of 46.67 mV/decade, a detection range of 10-4 - 10-2 M and a detection limit of 10-4 M, R2 = 99.62 %. The indicator electrode B3-4 has a sensitivity of 38.16 mV/decade, a detection range of 10-6 - 10-4 M and a detection limit of 10-6 M, R2 = 95.42 %. The best results on electrodes B1-4.