A graphene-charge carrier confinement induced by high-frequency photons and a subsequent clustering of artificial atoms in graphene plane have been studied using electrophysical and Raman-spectroscopy methods. To fabricate the graphene n-p-n junctions, commensurable superlattice structures consisting of multi-walled carbon nanotubes (MWCNTs) have been formed utilizing a Langmuir-Blodgett technique. It has been shown that the p-n graphene junctions are sensitive to graphene lattice-deformation defects only. The levels of graphene defect do not host impurity electrons. One offers a mechanism of graphene monolayer self-repairing after a radiation damage. This mechanism is based on an existence of topologically protected Compton scatterers in graphene plane.

Graphene sheets are a highly radiation-resistant material for prospective nuclear applications and nanoscale defect engineering. However, the precise mechanism of graphene radiation hardness has remained elusive. In this paper, we study the origin and nature of defects induced by gamma radiation in a graphene rolled-up plane. In order to reduce the environmental influence on graphene and reveal the small effects of gamma rays, we have synthesized a novel graphene-based nanocomposite material containing a bilayer of highly aligned carbon nanotube assemblies that have been decorated by organometallic compounds and suspended on nanoporous Al2O3 membranes. The bilayer samples were irradiated by gamma rays from a 137Cs source with a fluence rate of the order of 105 m−2s−1. The interaction between the samples and gamma quanta results in the appearance of three characteristic photon escape peaks in the radiation spectra. We explain the mechanism of interaction between the graphene sheets and gamma radiation using a pseudo-Majorana fermion graphene model, which is a quasi-relativistic N=3-flavor graphene model with a Majorana-like mass term. This model admits the existence of giant charge carrier currents that are sufficient to neutralize the impact of ionizing radiation. Experimental evidence is provided for the prediction that the 661.7-keV gamma quanta transfer enough energy to the electron subsystem of graphene to bring about the deconfinement of the bound pseudo-Majorana modes and involve C atoms in a vortical motion of the electron density flows in the graphene plane. We explain the radiation hardness of graphene by the topological non-triviality of the pseudo-Majorana fermion configurations comprising the graphene charge carriers.