The aim of the present study was to assess the level of pesticide residues in vegetables in the Almaty Region of Kazakhstan and to determine the potential health risks associated with the exposures to these pesticides. A total of 82 samples of cucumbers and tomatoes from top agro-based market and greenhouses were analysed using a gas chromatography–micro electron capture detector/nitrogen–phosphorous detector (GC-μECD/NPD), a multiresidue method to analyse 184 different pesticide types. The results indicated that more than half of samples (59 %) contained 29 pesticides, in which 10 are not registered in Kazakhstan, ranging from 0.01 to 0.88 mg kg−1, and 28 % contained pesticide residues above maximum residue levels (MRLs). The estimated daily intakes (EDIs) ranged from 0.01 % of the acceptable daily intake (ADI) for pyrimethanil to 12.05 % of the ADI for lambda-cyhalothrin. The most critical commodity is triazophos and flusilazole in tomatoes, contributing 70.8 and 42.5 % to the acute hazard index (aHI). The results provided important information on the current pesticide contamination status of two commonly consumed vegetables and pointed an urgent need to control the use of plant protection products applied, especially potentially persistent pesticides, such as endosulfan and dicofol. These results also show that the detected pesticides may be considered a public health problem.Electronic supplementary materialThe online version of this article (doi:10.1007/s10661-015-4818-6) contains supplementary material, which is available to authorized users.

Long highly-resolved proxies for runoff are in high demand for hydrological forecasts and water management in arid Central Asia. An accurate (R 2 =0.53) reconstruction of October-September discharge of the Ili River in Kazakhstan, 1779-2015, is developed from moisture-sensitive tree rings of spruce sampled in the Tian Shan Mountains. The fivefold extension of the gauged discharge record represents the variability of runoff in the Lake Balkhash Basin for the last 235 years. The reconstruction shows a 40 yr long interval of low discharge preceded a recent high peak in the first decade of the 2000s followed by a decline to more recent levels of discharge not seen since the start of the gauged record. Most reconstructed flow extremes (±2σ) occur outside the instrumental record (1936-2015) and predate the start of large dam construction (1969). Decadal variability of the Ili discharge corresponds well with hydrological records of other Eurasian internal drainages modeled with tree rings. Spectral analysis identifies variance peaks (highest near 42 yr) consistent with main hemispheric oscillations of the Eurasian climatic system. Seasonal comparison of the Ili discharge with sea-level-pressure and geopotential height data suggests periods of high flow likely result from the increased contribution of snow to runoff associated with the interaction of Arctic air circulation with the Siberian High-Pressure System and North Atlantic Oscillation.

No abstract

Wild populations of Malus sieversii [Ldb.] M. Roem are valued genetic and watershed resources in Inner Eurasia. These populations are located in a region that has experienced rapid and on-going climatic change over the past several decades. We assess relationships between climate variables and wild apple radial growth with dendroclimatological techniques to understand the potential of a changing climate to influence apple radial growth. Ring-width chronologies spanning 48 to 129 years were developed from 12 plots in the Trans-Ili Alatau and Jungar Alatau ranges of Tian Shan Mountains, southeastern Kazakhstan. Cluster analysis of the plot-level chronologies suggests different temporal patterns of growth variability over the last century in the two mountain ranges studied. Changes in the periodicity of annual ring-width variability occurred ca. 1970 at both mountain ranges, with decadal-scale variability supplanted by quasi-biennial variation. Seascorr correlation analysis of primary and secondary weather variables identified negative growth associations with spring precipitation and positive associations with cooler fall-winter temperatures, but the relative importance of these relationships varied spatially and temporally, with a shift in the relative importance of spring precipitation ca. 1970 at Trans-Ili Alatau. Altered apple tree radial growth patterns correspond to altered climatology in the Lake Balkhash Basin driven by unprecedented intensified Arctic Oscillations after the late 1970s.

No abstract