Hybrid organic-silica material modified by amino groups has been investigated as adsorbent of radionuclides 90 Sr, 90 Y and 137 Cs from aqueous solutions. The sorption ability of the organicsilica material in the pH range of 2-9 with thermostating is studied by static sorption method. Analysis of sorption kinetic curves of radionuclides for aminoxerogel has shown that sorption equilibrium is established in 3-3.5 h. It is shown that the mechanisms of radionuclides sorption on the organic-silica material are combined by the complex formation and ion-exchange mechanism. The amino containing organic-silica material can be recommended for the cleaning of surfaces and purification of water solutions contaminated with 90 Sr and 90 Y. Keywords Hybrid organic-silica material, radionuclides 90 Sr, 137 Cs and 90 Y, sol-gel method, amino containing xerogel, water purification
In this study, nano-sized particles of manganese oxyhydroxide (MnO(OH)) are synthesized. Sorption properties of this material towards 90 Sr and 137 Cs radionuclides in the pH range from 2 to 9 at a temperature of 293.15 K solution are studied. The time of sorption achievement equilibrium in the radionuclide sorbent system depends on the nature of sorbed cation, but does not exceed 60 min.
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