Two sets of silver–molybdate complexes with L = XR3 (X = P, As, Sb; R3 = Ph3, Ph2Py) and functionalized pyridine-based ligands have been studied with different techniques.
Screening of AgNO3/AgStBu solutions in DMF, DMSO and NMP resulted in an isolation of three novel nanosized silver/thiolate complexes with a torus-like {Ag20(StBu)10} core. The structures of [NO3@Ag20(StBu)10(NO3)9(DMF)6] (1) and...
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