The first metal complexes of cyclic selenium(II) imide ligands, [PdCl2{Se,Se'-Se4(NtBu)3}] and [PdCl2{Se,Se'-Se4(NtBu)4}], which are obtained from the reaction of Se(NtBu)2 with [PdCl2(NCPh)2], contain the novel Se-N heterocycles Se4(NtBu)3 and Se4(NtBu)4.
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