A new square-planar palladium complex salt, (C 8 H 20 N)[PdCl 3 (C 2 H 3 N)], has been formed with one of the Cl atoms in tetrachloridopalladate(II) replaced by an acetonitrile coordinated through the N atom. This compound could be a useful precursor for synthesis of palladium complexes. The complex salt crystallizes in the monoclinic P2 1 /c space group.
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