Natural dyes have attracted increasing worldwide attention because of the carcinogenicity and environmental effects of synthetic dyes. In this study, wool fabric was treated with tannin‐rich extracts of Punica granatum peel and walnut shell in combination with some mordants. The effect of various mordants on the colorimetric and antibacterial properties of wool fabrics was investigated. The results showed that pretreatment with metallic mordants substantially improved the dyeing and fastness properties of wool fabrics. The extracts of Punica granatum peel and walnut shell showed a significant antibacterial activity at 5% concentration. In addition, antibacterial activity was dramatically enhanced using metallic salts. The antibacterial activity of samples dyed with natural dyes and without any mordant was not good, while the mordanted samples with copper, aluminum and tin salts obtained considerable antimicrobial properties following lightening and washing fastness. The extracts of Punica granatum peel and walnut shell can be considered as viable alternatives instead of artificial antibacterial agents for hospital textiles as well as an effective anti‐odour agent for sports and household textiles.
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