No toxic compounds such as KCN and no thermal activation is required for the preparation of Au/MgF2 complexes by a simple and facile “incipient wetness impregnation” method in which hydrogen tetrachloroaurate (HAuCl4) is the gold precursor. One of the complexes prepared exhibits unique catalytic properties and serves as a heterogeneous catalyst for the highly diastereoselective one‐pot synthesis of (±)‐menthol from citronellal (see picture).
A sweet catalyst: A catalyst formed of Ru/functionalized silica-coated magnetite nanoparticles is highly efficient in the one-pot production of sorbitol and glycerol, starting from cellulose and in the absence of an external hydrogen source. The ease of recoverability of the catalyst from the solid residues, and its reuse without loss of activity or selectivity for several runs, is an important green element of the process.
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