This work discloses the first examples of an effective enantioselective oxy‐Heck–Matsuda reaction using a variety of styrenic olefins to generate chiral dihydrobenzofurans. The reaction proceeds in moderate to good yields, with high trans diastereoselectivity (up to 20:1) in enantioselectivities up to 90:10 using the N,N‐ligand pyrimidine‐bisoxazoline (PyriBox). The oxy‐Heck–Matsuda reactions were carried out under mild conditions and rather low catalyst loadings. The feasibility and practicality of the process is demonstrated by a concise total synthesis of the neolignan (−)‐conocarpan. X‐ray diffraction of an advanced brominated intermediate in the route to (−)‐conocarpan has allowed the unequivocal assignment of the absolute stereochemistry of the oxy‐Heck–Matsuda aryldihydrobenzofuran products. A rationale for the mechanism operating in these enantioselective oxy‐Heck–Matsuda reactions is also presented.magnified image

Brazil’s offshore wind resources are evaluated from satellite winds and ocean heat flux datasets. Winds are extrapolated to the height of modern turbines accounting for atmospheric stability. Turbine technical data are combined with wind and bathymetric information for description of the seasonal and latitudinal variability of wind power. Atmospheric conditions vary from unstable situations in the tropics, to neutral and slightly stable conditions in the subtropics. Cabo Frio upwelling in the southeast tends to promote slightly stable conditions during the spring and summer. Likewise, Plata plume cold-water intrusions in southern shelf tends to create neutral to slightly stable situations during the fall and winter. Unstable (stable) conditions are associated with weaker (stronger) vertical wind shear. Wind technical resource, accounting for atmospheric stability and air density distribution, is 725 GW between 0–35 m, 980 GW for 0–50 m, 1.3 TW for 0–100 m and 7.2 TW for the Brazilian Exclusive Economic Zone (EEZ). Resources might vary from 2 to 23% according to the chosen turbine. Magnitudes are 20% lower than previous estimates that considered neutral atmosphere conditions. Strong winds are observed on the north (AP, PA), northeast (MA, PI, CE, RN), southeast (ES, RJ) and southern states (SC, RS). There is significant seasonal complementarity between the north and northeast shelves. When accounting for shelf area, the largest integrated resource is located on the north shelf between 0–20 m. Significant resources are also found in the south for deeper waters.

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