The title MnIII compound, {[Mn(C18H18N2O4)(CH3COO)]·CH3OH}n, was synthesized by a reaction between mangan­ese(II) acetate and ethyl­enebis(4-meth­oxy­salicylaldimine). The structure is made up of bis­(4-meth­oxy­salicyldene)ethyl­enediaminatomanganese(III) units bridged by acetate groups, with Mn—N = 1.9786 (9), Mn—O = 1.8784 (10) and Mn—Oacetate = 2.056 (9) and 2.2571 (9) Å, forming a one dimensional polymer (–Mn–acetate–Mn–acetate–) along [100]. The MnIII atom is in a Jahn–Teller-distorted octa­hedral environment with cis angles ranging from 81.87 (4) to 96.53 (4)° and trans angles ranging from 166.11 (3) to 173.93 (3)°. The methanol solvent mol­ecule is hydrogen bonded to the phenolate O atom. In addition to this classical hydrogen bond, there are weak C—H⋯O inter­actions. The structure was determined from a crystal twinned by pseudo-merohedry.

The title mol­ecule, C24H20Cl2N4, lies on an inversion center in an extended trans conformation. In the crystal, weak C—H⋯Cl inter­actions connect the mol­ecules into chains along [010].

In the title compound, [Cu(C13H20N3O)Br], the Cu(II) atom is coordinated by three N atoms and one O atom from the deprotonated ligand derived from the Schiff base condensation of 3,3-imino­bis­(propyl­amine) and salicyl­aldehyde. The three N and the O atoms occupy equatorial positions, while the Br atom occupies an axial position. The amine H atoms form inter­molecular hydrogen bonds with the Br and O atoms of adjoining mol­ecules