We report the synthesis and structural characterisation of two titanium(IV) complexes. A new titanium(IV) complex bearing four picolinato ligands, denoted as Ti(pic) 4 , has been prepared under solvothermal conditions. This complex identified by single-crystal diffraction is a new example of an octacoordinated environment for titanium(IV) and is close to an ideal triangular dodecahedron. A second synthesis of a [a]
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