Four novel triterpene glycosides named bodinitins A (1), B (2), C (3), and D (4) were isolated from the roots of Schefflera bodinieri. Based on spectroscopic data, especially 1H−H COSY and 13C−1H COSY NMR, the structures of the glycosides have been determined as 28-O-[α-l-rhamopyranosyl-(1→4)-O-β-d-glucopyranosyl-(1→6)]-β-d-glucopyranoside of demethylisoaleuritolic acid (1), 28-O-[α-l-rhamopyranosyl(1→4)-O-β-d-glucopyranosyl(1→6)]-β-d-glucopyranoside of isoaleuritolic acid (2), 28-O-[α-l-rhamnopyranosyl(1→4)-O-β-d-glucopyranosyl(1→6)]-β-d-glucopyranoside of 3-oxo-8-demethylisoaleuritolic acid (3), and 28-O-[α-l-rhamopyranosyl(1→4)-O-β-d-glucopyranosyl(1→6)]-β-d-glucopyranoside of 3-oxoisoaleuritolic acid (4).