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A series of (allyl)­palladium­(II) complexes of anionic N-heterocyclic carbenes that contain a weakly coordinating borate moiety (WCA-NHC) were prepared by deprotonation of the carbene IPr with n-butyllithium in the 4-position, which was followed by addition of B­(C6F5)3 and reaction of the resulting lithium carbene–borate with [(η3-allyl)­Pd­(μ-Cl)]2 (allyl = 2-propenyl, 2-butenyl, 2-methyl-2-propenyl, 1-phenyl-2-propenyl). In polar solvents such as tetrahydrofuran, chloropalladate complexes of the type [Li­(THF)3]­[(WCA-NHC)­PdCl­(η3-allyl)] were formed, whereas the reactions in toluene afforded neutral complexes of the type [(WCA-NHC)­Pd­(η3-allyl)], which exhibit an intramolecular interaction with the N-aryl groups of the carbene ligands. The allyl-palladium complexes were employed as catalysts for the Buchwald–Hartwig amination of various aryl halides with morpholine.

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