New chiral-at-metal ruthenium indenyl PPh 3 phosphoramidite allenylidene complexes have been synthesized and structurally characterized. Through thermal ligand-exchange reactions with [RuCl(Ind)(PPh 3 ) 2 ], the phosphoramidite ligands
A new five‐coordinate square pyramidal Ru—phosphoramidite is prepared and successfully applied in the amination of propargylic acetates (I) with secondary amines.
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