Reaction of Co(OAc)2·4H2O and Hsal in a basic MeCN solution affords the hexadecanuclear wheel [Co16(sal)16(OAc)16]·16MeCN (1·16MeCN) that displays ferromagnetic nearest neighbour exchange and has pseudo-calixarene character. Symmetry equivalent wheels self-assemble...
Two new paths for coordination driven self-assembly reactions under the binding supports of 2-((1-hydroxy-2-methylpropan-2-ylimino)methyl)-6-methoxyphenol (H2L) have been discovered from reactions of Cu(ClO4)2·6H2O, NEt3 and GdCl3/DyCl3·6H2O in MeOH/CHCl3 (2:1) medium. Similar...
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