A series of N-heterotriangulenes decorated with 4-pyridyl anchors were synthesized and their performance in n-type TiO2- and ZnO-based dye-sensitized solar cells investigated.
Diels-Alder cycloaddition reactions of 1,3,5-hexatriynes with tetraphenylcyclopentadienone have been performed, and mainly gave 1,2-diethynyl-3,4,5,6-tetraphenylbenzene derivatives as products. The Diels-Alder reactions were optimized under conventional heating and microwave irradiation conditions, and showed good selectivity towards the central carboncarbon triple bond of the triyne. Empirical evidence suggests
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