<p>Macropores have important beneficial impacts on the hydrological cycle, since they reduce risks of waterlogging, surface runoff, soil erosion and flooding. On the other hand, macropore flow is also associated with significant ecosystem disservices, since it can dramatically accelerate the leaching of contaminants to surface water and groundwater. Several approaches to model preferential macropore flow have been developed. One approach is to use the kinematic wave equation, in which the kinematic exponent should depend on the exponent in a power law relationship between wetted macropore surface area and macropore saturation. Most model applications have relied on calibration of model parameters against measured data on water flow. This makes critical testing of the underlying model concepts difficult and raises the question of whether the model is matching the data for the right reasons or not. In this study, we used X-ray tomography to quantify water and air distributions in macropores at varying steady-state flow rates in two topsoil and two subsoil columns (diameter 9 cm) sampled from a clay soil. We collected sufficient data to derive the kinematic wave exponent from the image data for the two topsoil samples. We found that the wetted macropore surface area and macropore saturation were indeed related by a power law for the first three irrigation intensities, corresponding to kinematic exponents of 1.22 and 1.26, respectively. These promising results need to be verified in future experiments that should be conducted on soil samples with smaller diameters to achieve better image resolutions and signal-to-noise ratios.</p>
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