A convenient synthesis of different types of α-amino phosphonates via one-pot solvent-free three component reactions of aldehydes, amines and phosphites catalyzed by bismuth salts has been investigated. Bismuth triflate is found to be the most effective catalyst for this reaction.

A simple and efficient microwave-induced ruthenium trichloride-catalyzed synthesis of pyrrole fused with indole system in water is developed by reacting commercially available isatin and 4-hydroxyproline.

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