The investigation of cubic spherical submicron particles of non-doped Y2O3and Y2O3doped with Eu3+in a TEM using CL from individual particles is described.
An oxide/oxysulfide based phosphor triad with particle sizes of around 1micrometer (green Y 2 SiO 5 :Tb or Y 2 O 2 S:Tb, and blue Y 2 SiO 5 :Ce) down to 250nm for the red Y 2 O 3 :Eu is reported. These phosphors perform well in brightness under the conditions necessary for use in FED's and are of suitable size for use in high definition screens. We also report a green emitting Y 2 O 2 S:Tb phosphor that has been prepared by a new method involving homogeneous precipitation of the precursors and a new firing regime. The resulting cathodoluminescent phosphor having submicrometer size particles has a luminous efficiency of 34.6 lm/W at an electron beam accelerating voltage of 5000 V.
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