Photolysis of [((~5-C5H,)Fe(CO)2}2] in CH4 (1 2 K) and polyvinyl chloride film (12-77 K) matrices leads to the formation of a novel species proposed, on the basis of i.r. evidence including I3CO enrichment and u.v.visible spectra, to be the CO-bridged dimerA recent flash photolysis study1 of the photochemistry of [ ((q5-C5H5)Fe(CO), >,I (1) provided evidence for two distinct
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