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Bioethanol is becoming increasingly attractive for the reasons of energy security, diversity, and sustainability. As a result, the use of bioethanol for transportation purposes has been encouraged extensively. However, designing an effective bioethanol supply chain that is both sustainable and robust is still questionable. Therefore, this research focuses on designing a bioethanol supply chain that is: 1) sustainable in improving economic, environmental, social, and energy efficiency aspects; and 2) robust to uncertainties such as bioethanol price, bioethanol demand and biomass yield.