The thermodynamic state of a triglycine sulphate crystal, previously
exposed to an electric field parallel to the non-ferroelectric
c-axis,
has been investigated. The frozen ferroelectric
c-domains
have been observed by a liquid crystal technique and under the scanning electron
microscope. Pyroelectric properties and polarization in the non-ferroelectric direction
have been investigated. Regions of dipoles that are strongly correlated along the
c-direction as well as the
clamping of the b-polarization
switching have been found to be accompanied by permanent transverse
polarization.
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