Zero-field electrical resistivity over the temperature range of 4–300 K and magnetoresistance in magnetic fields of up to 12 T have been measured in Gd5(Si1.8Ge2.2). This system undergoes a first-order magnetostructural transition at TC≅240 K, from a high-temperature paramagnetic to a low-temperature ferromagnetic phase, accompanied by a large drop in the resistivity. The application of an external magnetic field above TC can induce this transition, and a giant negative magnetoresistance effect (Δρ/ρ≅−20%) is observed associated with this first-order field-induced transition.
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