Injection currents in organic crystals have been measured t o determine the rate of hole exchange with metal contacts evaporated in high vacuum. At a gold contact the rate of hole injection increased with decreasing ionisation energy of the organic crystal but was depending on the evaporation procedure due t o an influence of residual gas molecules. The excitation spectrum of the photocurrent agreed with hole generation through triplet excitons. Below the So-S, transition hole generation was due t o surface states in the band gap. Der Anstausch von Defektelektronen zwischen organischen Kristallen und im Hochvakunm aufgedampften Metallkontakten wurde als Injektionsstrom gemessen. Die Defektelektronen-Injektion &us einem Gold-Kontakt nahm mit abnehniender Ionisierungsenergie des organischen Kristalls zu, wobei jedoch eine Abhangigkeit von den Aufdampfbedingungen den EinfluB von Restgasmolekiilen erkennen lieB. Das Anregungsspektrum des Photostroms entsprach einer Defektelektronen-Erzeugung durch Triplett-Exzitonen. Unterhalb dea S, -S, ubergangs geschah die Defektelektronen-Erzeugung iiber Oberflachenzustande. l ) Berlin-Dahlem, Faradayweg 4-6.
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