The CMS Zero Degree Calorimeters, ZDCs, will measure photons and neutrons emitted with |η| ≥ 8.6 from Pb+Pb, p+Pb and p+p collisions at √ s N N = 5.5, 8.8 and 14 TeV respectively. The calorimeter consists of an electromagnetic part segmented in the horizontal direction and an hadronic part segmented into four units in depth. In addition CMS will have access to data from a segmented shower maximum detector being built for luminosity measurements. We will present detailed results from tests beam measurements taken at the CERN SPS. These data will be used to extrapolate the utility of the ZDCs to measure photons, and possibly π 0 s in p+p and ultra-peripheral heavy-ion collisions. Data from the hadronic section can be used to estimate the number of participants in heavy ion-collisions. In addition we will discuss plans to use the detector to measure the reaction plane, thereby extending the sensitivity of the central detectors in CMS.