B.V.D. Vijaykumar scite author profile

In this work, a new family of polyhedral oligomeric silsesquioxanes (POSS) based esters have been synthesized that consists eight ester functional groups. These are classified into Type-I and Type-II esters based on the starting materials, octakis(3-chloropropyl)silsesquioxane (Cl-POSS) and octakis(3-hydroxypropyldimethylsiloxy) octasilsesquioxane (OHPS) respectively. These new POSS type ester moieties can be used as insulating oils and oil additives in the transformers and also considered to be alternatives to mineral and vegetable oils that are presently used in the insulation system.

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Environmentally benign perfluorooctanesulfonate alternatives using a Zn/CuI mediated Michael-type addition in imidazolium ionic liquids

Vijaykumar

Premkumar

Jang

et al. 2014

Green Chem.

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Design, synthesis and surfactant properties of perfluorobutyl-based fluorinated sodium alkanesulfonates

Chirumarry

Rao

et al. 2017

Journal of Fluorine Chemistry

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B.V.D. Vijaykumar

Synthesis of a novel compound based on chitosan and ammonium polyphosphate for flame retardancy applications

One-pot conversion of phenols to anilines via Smiles rearrangement

Synthesis of POSS Derived Organic-Inorganic Hybrid Esters for Insulating Oil Applications

Environmentally benign perfluorooctanesulfonate alternatives using a Zn/CuI mediated Michael-type addition in imidazolium ionic liquids

Design, synthesis and surfactant properties of perfluorobutyl-based fluorinated sodium alkanesulfonates

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