The catalytic disproportionation of H2O2 to O2 and H2O is achieved with the asymmetric hemerythrin model complex 1, which has a reactive coordination site. The catalytic cycle proceeds via the oxyhemerythrin form with a coordinated hydrogenperoxo ligand. L 1,4,7‐trimethyl‐1,4,7‐triazacyclononane, bpy 2,2′‐bipyridine.
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Die katalytische Zersetzung von H2O2 zu O2 und H2O gelingt mit dem asymmetrischen Hämerythrinmodellkomplex 1, der eine labile Koordinationsstelle hat. Beim Katalysecyclus wird die Oxyhämerythrinform mit koordiniertem Hydroperoxidoliganden durchlaufen. L = 1,4,7‐Trimethyl‐1,4,7‐triazacyclononan, bpy= 2,2′‐Bipyridin.
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