111822-64-1; [PPN]2[Re7C(CO)21Rh(COD)], 111793-56-7; [PP-N]2[Re7C(CO)21Pd(C3H5)], 111793-54-5; [PPN]2[Re7C(CO)21Pt-(C4H7)], 111793-55-6; [PPN]2[Re7C(CO)21uRe(CO)3], 111765-68-5. Supplementary Material Available: Tables listing atomic coordinates, bond distances, and bond angles and a figure of variable-temperature 13C NMR spectra of [PPN]2[Re7C(CO)21-Rh(COD)] (7 pages); tables of observed and calculated structure factors (20 pages). Ordering information is given on any current masthead page.
Die Behandlung von Ru3(CO)" (I) oder Os3(CO)12 (V) mit Na in Ether‐Lösu‐ngsmitteln wird als wirksamer Syntheseweg für große anionische Carbonylcluster beschrieben.
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