Improved quantification of the factors controlling soil organic matter (SOM) stabilization at continental to global scales is needed to inform projections of the largest actively cycling terrestrial carbon pool on Earth, and its response to environmental change. Biogeochemical models rely almost exclusively on clay content to modify rates of SOM turnover and fluxes of climate-active CO 2 to the atmosphere. Emerging conceptual understanding, however, suggests other soil physicochemical properties may predict SOM stabilization better than clay content. We addressed this discrepancy by synthesizing data from over 5,500 soil profiles spanning continental scale environmental gradients. Here, we demonstrate that other physicochemical parameters are much stronger predictors of SOM content, with clay content having relatively little explanatory power. We show that exchangeable calcium strongly predicted SOM content in water-limited, alkaline soils, whereas with increasing moisture availability and acidity, iron-and aluminum-oxyhydroxides emerged as better predictors, demonstrating that the relative importance of SOM stabilization mechanisms scales with climate and acidity. These results highlight the urgent need to modify biogeochemical models to
[1] Snow cover duration in a seasonally snow covered mountain range (San Juan Mountains, USA) was found to be shortened by 18 to 35 days during ablation through surface shortwave radiative forcing by deposition of disturbed desert dust. Frequency of dust deposition and radiative forcing doubled when the Colorado Plateau, the dust source region, experienced intense drought (8 events and 39-59 Watts per square meter in 2006) versus a year with near normal precipitation (4 events and 17-34 Watts per square meter in 2005). It is likely that the current duration of snow cover and surface radiation budget represent a dramatic change from those before the widespread soil disturbance of the western US in the late 1800s that resulted in enhanced dust emission. Moreover, the projected increases in drought intensity and frequency and associated increases in dust emission from the desert southwest US may further reduce snow cover duration.Citation: Painter, T.
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