Charles H. Brown scite author profile

A survey of a series of organosilyl derivatives of serine and tyrosine has shown that they have a satisfactory stability profile for use in peptide synthesis. Only when alkaline conditions were used did side-reactions appear. A range of stability profiles have been determined from a study of organosilyl derivatised dipeptides under different conditions, giving t4-values for hydrolysis ranging from 41 to 465 min in acid conditions, yet giving long-term stability at pH-values near to neutrality.

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A highly diastereoselective addition of [E]- and [Z]-crotyldiisopinocampheylboranes to .alpha.-substituted aldehydes

Brown¹,

Bhat²,

Randad³

1987

J. Org. Chem.

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The Wittig reaction of o-formylbenzyltriphenylphosphonium chloride

Brown¹,

Sargent²

1969

J. Chem. Soc., C

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Vinylic organoboranes. 14. A stereospecific synthesis of (E)-1-halo-1-alkenes from 1-alkynes

Brown¹,

Hamaoka²,

Ravindran³

et al. 1989

J. Org. Chem.

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Charles H. Brown

A human skin multifunctional O-acyltransferase that catalyzes the synthesis of acylglycerols, waxes, and retinyl esters

Protection of hydroxy groups by silylation: use in peptide synthesis and as lipophilicity modifiers for peptides

A highly diastereoselective addition of [E]- and [Z]-crotyldiisopinocampheylboranes to .alpha.-substituted aldehydes

The Wittig reaction of o-formylbenzyltriphenylphosphonium chloride

Vinylic organoboranes. 14. A stereospecific synthesis of (E)-1-halo-1-alkenes from 1-alkynes

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