Base-Catalyzed Autoxidation of 20-Hydroxyecdysone: Synthesis of Calonysterone and 9,20-Dihydroxyecdysone.-Stirring a basic solution of 20-hydroxyecdysone (I) under the conditions shown results in autoxidation to yield the title compounds ( II) and (III). Calonysterone (II) is a rare ecdysteroid isolated from e.g. Vitex glabrata and required for structure-activity studies. -(SUKSAMRARN, A.; GANPINYO, P.; SOMMECHAI, C.; Tetrahedron Lett. 35 (1994) 25, 4445-4448; Dep. Chem., Fac. Sci., Ramkhamhaeng Univ., Bangkok 10240, Thailand; EN)
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