HAL is a multidisciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. L'archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d'enseignement et de recherche français ou étrangers, des laboratoires Influence of alkaline earth metal ions on structures and luminescent properties of Na m M n UO 2 (CO 3) 3 (4-m-2n)-(M = Mg, Ca; m, n = 0-2): time-resolved fluorescence spectroscopy and ab initio studies
The formation constants of CaUO2(CO3)32− and Ca2UO2(CO3)3(aq) were determined in NaCl medium at ionic strengths between 0.1 and 1 mol kgw−1 using time-resolved laser-induced luminescence spectroscopy (TRLS).
The formation constants and specific ion interaction coefficients of MgUO2(CO3)32 complex were determined in 0.1 to 1 mol kgw-1 NaCl and 0.1 to 2.21 mol kgw-1 NaClO4 media in the...
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