In this work, three-dimensional N, S co-doped carbon with high density Fe-single atom-nanoclusters of homogenous dispersion (N, S co-doped CPANI-TA-Fe Fe-SA-NC catalysts) is successfully prepared by the optimal pyrolysis of...
In this work, uniform ultra-small core-shell Au-Pt nanoparticles (denoted as USCS Au-Pt NPs) with Au-decorated Pt surfaces are successfully prepared by Fe(II)-assisted one-pot co-reduction of Au(III) ions and Pt(II) ions...
In this work, S-doped AuPbPt alloy nanowire-networks (NWNs) are synthesized by conformal growth of Pt onto S-doped AuPb NWNs as templates, which are obtained by NaBH4 reduction of an extended...
In this work, quasi-spherical, uniform gold nanoparticles
with rich deformation twinning (Audt NPs) were first synthesized
with the assistance of copper(II) ions. Then, these Audt NPs were used as the cores for the fabrication of core–shell
(CS) Audt–Pd NPs with ultrathin Pd layers, which
also can bear compressive strain because of the formation of corrugated
structured Pd shells led by the lateral confinement imposed by deformation
twinning in the Au cores. The
presence of compressive strain in the CS Audt–Pd
NPs can result in the widening of the d-band width of the Pd shell
and further the downshift of their d-band center, which can then improve
the desorption ability of intermediates and still maintain the adsorption
ability of the reactants because of the broad adsorption potential
range. Taking the oxidation reduction reaction and the ethanol oxidation
reaction as examples, the as-prepared Audt–Pd NPs
indeed exhibited superior catalytic performances because of the synergism
of compressive strain and the electronic effect. Thus, our work opens
a new way to introduce compressive strain in the Pd-based CS NP catalysts,
which can achieve the enhancement in the electrocatalytic performance
by combining the merit of compressive strain and the electronic effect.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.