The purpose of this study was to investigate the e-learning method in math to implement the curriculum articulation between junior high school and senior high school, and evaluated its learning effects to improve the implement method of curriculum articulation, to strengthen the students’ digital mathematical materials of curriculum articulation and to quantify the analyses of the students’ learning effects. The research strategies firstly concentrate on interviews to set up teaching content units; secondly evaluate and establish e-learning administrative platform, and then design e-learning materials in ADDIE systems. By previewing and revising contents of these materials, they are practically used in the library activities. In addition to record the pretest and post-test scores of the learners, the data of on-line voting are collected in order to do the comparative analyses to form conclusions as reference for the related researches.The research result showed that using e-learning methods to implement curriculum articulation activities got positive improvement not only in human efforts but also in materials and time; besides, the methods inspired the learners’ motivation, strengthened the learning effects and got the positive satisfaction in the whole learning activities. Researchers suggest that the related researches should be conducted continually so as to meet problems of curriculum articulation in new curriculum of senior high school and help those students who are in need to do automatically learning. Gradually, it can promote school into the learning resources center in the community. I