Tertiary alcohols react with stoichiometric BF 3 AEEt 2 O and N-hydroxyphthalimide to yield N-alkoxyphthalimides. Sub sequent hydrazinolyses afford the title compounds.
Hydroxylamine derivatives Q 0110A Facile Synthesis of (tert-Alkoxy)amines. -A straightforward two-step method is described for the transformation of tertiary alcohols to (tert-alkoxy)amines. -(PALANDOKEN, H.; BOCIAN, C. M.; MCCOMBS, M. R.; NANTZ*, M. H.; Tetrahedron Lett. 46 (2005) 39, 6667-6669; Dep. Chem., Univ. Calif., Davis, CA 95616, USA; Eng.) -Mais 01-081
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