Control of single-walled carbon nanotube dispersion properties is of substantial interest to the scientific community. In this work, we sought to investigate the effect of a macrocycle, pillar[5]arene, on the dispersion properties of a polymer–nanotube complex. Pillar[5]arenes are a class of electron-rich macrocyclic hosts capable of forming inclusion complexes with electron-poor guests, such as alkyl nitriles. A hydroxyl-functionalized pillar[5]arene derivative was coupled to the alkyl bromide side chains of a polyfluorene, which was then used to coat the surface of single-walled carbon nanotubes. Noncovalent functionalization of carbon nanotubes with the macrocycle-containing conjugated polymer significantly enhanced nanotube solubility, resulting in dark and concentrated nanotube dispersions (600 μg mL –1 ), as evidenced by UV–vis–NIR spectroscopy and thermogravimetric analysis. Differentiation of semiconducting and metallic single-walled carbon nanotube species was analyzed by a combination of UV–vis–NIR, Raman, and fluorescence spectroscopy. Raman spectroscopy confirmed that the concentrated nanotube dispersion produced by the macrocycle-containing polymer was due to well-exfoliated nanotubes, rather than bundle formation. The polymer–nanotube dispersion was investigated using 1 H NMR spectroscopy, and it was found that host–guest chemistry between pillar[5]arene and 1,6-dicyanohexane occurred in the presence of the polymer–nanotube complex. Utilizing the host–guest capability of pillar[5]arene, the polymer–nanotube complex was incorporated into a supramolecular organogel.

Keyword: electrodeposition, wet ionic liquid, possible application to mining wastes https://mc06.manuscriptcentral.com/cjc-pubs We investigated the deposition of silver, copper, and lead from the ionic liquid 1-11 ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide [EMIM][TFSI] under 12potentiostatic conditions in the presence of water. This was part of a larger project 13 involving the extraction of metal ions from mining waste into an ionic liquid, followed by 14 electrodeposition so that the ionic liquid could be recycled. All three elements were 15 deposited in metallic form by electrolysis in the ionic liquid, and the process was 16

No abstract