Resonance Raman spectra obtained using laser excitation wavelengths varied to match each of two visible charge transfer absorption bands of a dmeric metal complex with two different diimine ligands vary significantly. The identification of characteristic ligand vibrations leads to the assignment of the two metal-to-ligand charge transfer transitions with respect to the ligand which accepts the charge in the excited state. The resonance Raman spectra provide information relating to the complex structures in Solution.