Compound[Ag 44 (W 10 O 32 )(S t Bu) 24 (CF 3 COO) 8 ](CF 3 COO) 6 • 6H 2 O (1) was synthesized through a one-pot method. This is the first case of isolating a new silver thiolate cluster containing a [W 10 O 32 ] 6À template which transforms from WO 4 2À polyoxoanion through a self-assembly process. The anionic nature of the reduced [W 10 O 32 ] 6À template and the effective silver-oxygen interaction contribute to the formation of the Ag 44 nanowheel in 1. The luminescence, photocatalytic activity and electrochemistry properties of 1 were studied.[a] J.

Three trinuclear silver nanoclusters, [Ag3(dppm)3(tBuC≡C)](CF3SO3)2 (1), [Ag3(dppm)3(CO3)(CH3OH)](CF3SO3)•H2O (2) and [Ag3(dppm)3(Cl)2](CF3SO3)•3DMF (3) (dppm = 1, 2-bis-(diphenylphosphino)methane) have been obtained, which also have been characterized by a series of techniques including single-crystal...

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