Metal–organic nanoparticles (see SEM image) showing valence‐tautomeric behavior have been obtained by a versatile approach involving precipitation and coordination polymerization. They undergo reversible temperature‐dependent interconversion between low‐ and high‐spin forms, as revealed by plotting the magnetic moment χ as a function of temperature.
Metall‐organische Nanopartikel (siehe SEM‐Bild) mit Valenztautomerie wurden durch Fällung und Bildung eines Koordinationspolymers erhalten. Die Auftragung des magnetischen Moments χ gegen die Temperatur zeigt, dass die Partikel einen reversiblen Low‐Spin/High‐Spin‐Übergang eingehen.
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