The superposition model was originally developed to separate the geometrical and physical information in crystal field parameters. Its success in the analysis of lanthanide spectra has been paralleled by the success of the related angular overlap model in the analysis of d-electron spectra. The basic ideas, method of application and reliability of the superposition model are discussed and its relationship with the angular overlap model is clarified.Recent developments, described in this review, are the application of the superposition model to the ground ( L = 0) multiplet splittings of d5 and f 7 ions, orbit-lattice interactions, transition intensities and correlation crystal fields. Special attention is paid to work which has been claimed to support or disprove the postulates of the model.
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