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Electrical and switching property of amorphous defect chalcopyrite ZnGa 2 Te 4 thin films prepared by thermal evaporation technique has been studied. The elemental chemical compositions of the prepared bulk as well as the asdeposited film were determined by means of energy dispersive X-ray spectrometry. X-ray diffraction pattern revealed that the powder compound is polycrystalline and the asdeposited and the annealed films at t a B 548 K have the amorphous phase, while that the annealed at t C 573 K are polycrystalline with a single phase of a defect chalcopyrite structure similar to that of the synthesized material. The great advantage of this material is the capability to appear in two different phases, the amorphous and the crystalline phases, with rather different electrical properties. Both dynamic and static I-V characteristics and the switching phenomenon at 601 nm are investigated. The threshold switching mechanism was explained by a thermal model of switching, i.e., joule heating with an electrically conducting channel. ZnGa 2 Te 4 is good candidate in phase change memory device.

In this article, we report the preparation and characterization of novel Li-stuffed garnets LiLaTaGdO (0 ≤ x ≤ 0.55) for all-solid-state Li ion batteries. The conventional solid-state method was used to prepare LiLaTaO in air at 1200 °C and LiLaTaGdO at 1150 °C. Rietveld refinements for the powder X-ray diffraction (PXRD) patterns confirmed the formation of a cubic garnet-like structure (space group Ia3[combining macron]d) with cell constant increased from 12.8176(4) Å (x = 0) to 12.9372(2) Å (x = 0.55). However, small amounts of second phases were observed for higher Gd-doped samples. Scanning electron microscopy revealed that LiLaTaGdO exhibits the highest density among all investigated samples in this study. The AC impedance spectroscopy data of the samples have been analyzed in relation to ionic conductivity, dielectric constants, and loss tangent. Among the investigated electrolytes, the LiLaTaGdO composition demonstrated the highest bulk ionic conductivity of 8.18 × 10 S cm at 25 °C, which is significantly higher than that of the parent garnet LiLaTaO (1.65 × 10 S cm at 25 °C). The appearance of a relaxation peak in the loss tangent plots for all samples seems to be due to the dipolar rotations of Li ions in Li-stuffed garnets.