The concentration of indoor suspended particulate matter is considered to be one of the main factors that affect health and quality of life. In Poland, in response to the pressure of public opinion, a few thousand air purifiers have been installed in public buildings where children spend time. However, another factor that also impacts upon the quality of indoor air, namely increased CO2 mixing ratios, is frequently overlooked. The only way to remove CO2 excess from interiors is through intensive ventilation. This is often an action at odds with the need to maintain low concentrations of particulate matter in indoor air. Two methods are presented to assess the rate of air exchange using CO2 or particulate matter as a tracer. One of the methods using indoor/outdoor PM (particulate matter) concentrations is based on the use of box models for analysis. The second one uses indoor CO2 concentration change analysis. At the tested locations, they showed large deviations of the determined values of the air exchange coefficients from its limits. Both methods showed consistent ventilation parameters estimation.
The objective of this research was to evaluate the seasonal variation of the chemical composition of PM10 including polycyclic aromatic hydrocarbons (PAHs) and 1,3,5-triphenylbenzene (135TPB), which is a well known marker of plastic combustion. The presented work is a part of the project concerning assessment of air quality of small cities around Krakow agglomeration. Monitoring campaign was conducted between February and October 2017 in Wadowice, a small city in Krakow agglomeration, South Poland. To widen the knowledge of Krakow's agglomeration air quality, other aerosol chemical components were analyzed. Ion chromatography (IC) was used for analysis of cations and anions, while gas chromatography-mass spectrometry (GC-MS) was used for PAHs. Samples were also analyzed for OC/EC (organic/elemental carbon) by thermal-optical analysis with a Sunset Laboratory carbon analyzer, Sunset Inc. The co-combustion of plastic in addition to conventional fuels and the respective impact on air quality is evaluated via the concentration of the marker compound 135TPB. Co-combustion of plastics with fuels resulted in a higher abundance of fluorene and most of 4-6 ring PAHs, in agreement with recent literature. Authors proved that other sources besides plastic burning, including road transport, residential heating, residential combustion, industrial emissions, affect the air quality in South Poland. The modeling tool Hybrid Single-Particle Lagrangian Integrated Trajectory model (HYSPLIT), developed by NOAA's Air Resources Laboratory, was used to define the possible areas outside Wadowice contributing to urban air pollution.
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