The electronic conductivity of two isostructural interdigitated coordination polymers based on a novel tetrathiafulvalene derivative and M(NCS)2 nodes (M = Fe, Co) is enhanced upon surface oxidation of the crystals by iodine.

A novel tetrathiafulvalene derivative bearing four 4-thiopyridyl units has been assembled with Cd(ii) salts for the construction of a series of coordination polymers with different structural organization depending on the ligand conformation.

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Two novel hetero- and homoleptic Au(III) complexes based on a dithiolene ligand bearing two 4-thiopyridyl groups have been designed, synthesized and characterized in solution and in the crystalline state. These...