No abstract

No abstract

RESUMOFrente à crescente necessidade de recuperar o meio ambiente e seus recursos naturais, atualmente a reciclagem e reutilização dos materiais torna-se uma das soluções sustentáveis mais visadas. Neste cenário, o processamento de compósitos particulados de alumínio em matriz termoplástica de polietileno de baixa densidade (PEBD), provenientes da reciclagem de embalagens longa vida, apresenta-se de maneira atrativa para a obtenção de matéria prima para a construção civil, na fabricação de telhas de baixo peso, associado a baixo custo e elevada disponibilidade, dentre outras aplicações. Este trabalho tem por objetivo estudar as propriedades e o comportamento do compósito de polietileno de baixa densidade/alumínio reciclados. Com este objetivo, foi realizada a avaliação morfológica do compósito a partir de microscopia óptica (MO), microscopia eletrônica de varredura (MEV) e espectroscopia por energia dispersiva de raios X (EDS), bem como avaliados os comportamentos térmico e mecânico deste material após estes terem sido submetidos à climatização higrotérmica e por radiação ultravioleta (UV). Para a avaliação térmica foram empregadas técnicas de análise termogravimétrica (TGA) e calorimetria exploratória diferencial (DSC). As propriedades mecânicas foram avaliadas por análise dinâmico-mecânica (DMA) e ensaios de tração e impacto. A partir dos resultados obtidos por meio deste trabalho pode-se concluir que o intemperismo envolvendo umidade e radiação UV pode influenciar nos desempenhos térmico e mecânico do compósito de Alumínio/PEBD, porém, foi observado que esta influência não é suficiente para inviabilizar a utilização destes materiais na construção civil, garantindo este mercado para o compósito de PEBD/Al. Palavras-chave:Reciclagem, compósito PEBD/Al, condicionamento higrotérmico e UV. ABSTRACTFace the growing need to restore the environment and its natural resources, currently the recycling and reuse of materials becomes one of the most important sustainable solution. In this scenario, the processing of aluminum particulate composite with low density polyethylene thermoplastic matrix (LDPE) from recycling packages, presents an attractive way to obtain raw materials for the building industry, in the manufacturing of lightweight roof tiles, associated with low cost and high availability, among other applications. This work aims to study the properties and behavior of recycled low density polyethylene/aluminum composite. In order to do this, they were performed composite morphology assessment through optical microscopy (OM), scanning electron microscopy (SEM) and energy-dispersive x-ray spectroscopy (EDS), as well as were evaluated the thermal and mechanical behavior of this material after being subjected to hygrothermal and ultraviolet conditioning (UV). For the thermal evaluation was performed thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The mechanical properties were evaluated by dynamic mechanical analysis (DMA) and tensile and impact tests. From the results obtained from thi...

Factors such as project and execution errors, lack of maintenance and inspection, and increases in loading can cause deficiencies to reinforced concrete structures. In this regard, there is the necessity of the application of structural reinforcement systems. This manuscript aims at the structural capacity analyses involving the bending of steel-reinforced concrete beams with additional reinforcement of polymer composites using glass and carbon fibers, and its comparison with regular reinforced concrete beams. Steel-reinforced concrete, polymeric composite, and hybrid beams (steel-reinforced concrete and polymeric composite combined) were submitted to the four-points bending test. Experimental and calculated results for the dimensioning of the beams were compared, allowing the validation of the calculation method and its implementation. It was possible to notice both the efficiency of the composite material applied as reinforcement, as well as the efficiency of the calculation models applied in this work.

The industries that have polymers as an important raw material in their production, such as the construction, automotive, electrical and electronic sectors, always seek innovations to cut costs, reduce weight, easiness of processing, maximizing mechanical properties, and recyclability. In this context, this work presents the study of the kinetic parameters and viscoelastic behavior of a new thermoplastic system initially liquid. Through differential scanning calorimetry (DSC) analysis, Brookfield viscosimetry; dynamic-mechanical analysis (DMA) and mathematical modeling with consolidated and standardized methods, it was possible to evaluate the polymerization kinetics and viscoelastic behavior of the material in solutions with different concentrations. The generated equations allow the prediction of the kinetic and gelation behavior of the material reducing the need for laboratory tests to determine polymer properties. The found results showed that concentrations of benzoyl peroxide initiator with 1wt% in the methyl methacrylate (MMA) copolymer solution have the best viscoelastic and dynamic-mechanical properties with a less expensive polymerization cycle.