Metal-free room-temperature phosphorescence (RTP) materials offer unprecedented potentials for photoelectric and biochemical materials due to their unique advantages of long lifetime and low toxicity. However, the achievements of phosphorescence at ambient condition so far have been mainly focused on ordered crystal lattice or on embedding into rigid matrices, where the preparation process might bring out poor repeatability and limited application. In this research, a series of amorphous organic small molecular compounds were developed with efficient RTP emission through conveniently modifying phosphor moieties to β-cyclodextrin (β-CD). The hydrogen bonding between the cyclodextrin derivatives immobilizes the phosphors to suppress the nonradiative relaxation and shields phosphors from quenchers, which enables such molecules to emit efficient RTP emission with decent quantum yields. Furthermore, one such cyclodextrin derivative was utilized to construct a host-guest system incorporating a fluorescent guest molecule, exhibiting excellent RTP-fluorescence dual-emission properties and multicolor emission with a wide range from yellow to purple including white-light emission. This innovative and universal strategy opens up new research paths to construct amorphous metal-free small molecular RTP materials and to design organic white-light-emitting materials using a single supramolecular platform.
a b s t r a c tThe concept of an intuitionistic fuzzy number (IFN) is of importance for quantifying an ill-known quantity, and the ranking of IFNs is a very difficult problem. The aim of this paper is to introduce the concept of a triangular IFN (TIFN) as a special case of the IFN and develop a new methodology for ranking TIFNs. Firstly the concepts of TIFNs and cut sets as well as arithmetical operations are introduced. Then the values and ambiguities of the membership function and the non-membership function for a TIFN are defined. A new ranking method is developed on the basis of the concept of a ratio of the value index to the ambiguity index and applied to multiattribute decision making problems in which the ratings of alternatives on attributes are expressed with TIFNs. The validity and applicability of the proposed method, as well as analysis of the comparison with other methods, are illustrated with a real example.
The concept of intuitionistic fuzzy sets is the generalization of the concept of fuzzy sets. The theory of intuitionistic fuzzy sets is well suited to dealing with vagueness. Recently, intuitionistic fuzzy sets have been used to build soft decision making models that can accommodate imprecise information, and two solution concepts about the intuitionistic fuzzy core and the consensus winner for group decision-making have also been developed by other researchers using intuitionistic fuzzy sets. However, it seems that there is little investigation on multicriteria and/or group decision making using intuitionistic fuzzy sets with multiple criteria being explicitly taken into account. In this paper, multiattribute decision making using intuitionistic fuzzy sets is investigated, in which multiple criteria are explicitly considered, several linear programming models are constructed to generate optimal weights for attributes, and the corresponding decision-making methods have also been proposed. Feasibility and effectiveness of the proposed method are illustrated using a numerical example.
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