Pyrazole and Pyrazolyl Complexes of Ruthenium to 16.2 for An). When the macrocyclic ligand is L2, the activation enthalpy increases over that for Lb as discussed earlier, but is still substantially less than those observed for TAAB. Apparently, then, Lb and to a lesser extent L2, exerts a stronger labilizing influence on N-donor axial ligands than does TAAB.
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